Green S E142
synthetic β Primarily synthetic.
Sodium salt of N-[4-[[4-(dimethylamino)phenyl](2-hydroxy-3,6-disulfo-1-naphthalenyl)methylene]-2,5-cyclohexadien-1-ylidene]-N-methylmethanaminium
CAS: 3087-16-9
Factual Regulatory Reference
This database provides factual regulatory information compiled from official government sources. It does not constitute medical, nutritional, or safety advice. Regulatory status varies by country and is subject to change. Always refer to your local regulatory authority for the most current information.
? Did You Know?
Beyond food, Green S is also used in cosmetics, industrial applications. Its versatility makes it one of the most multi-purpose chemical compounds in everyday life.
Regulatory opinions differ: Green S is approved in EU but banned in USA, JAPAN, CANADA. This reflects different risk assessment philosophies between regions.
To reach the Acceptable Daily Intake limit, a 60kg adult would need to consume approximately ~30 servings of canned peas (100g at 100mg/kg) in a single day. (This is a mathematical illustration, not a safety recommendation.)
Regulatory Analysis
Green S epitomizes the regulatory paradox of how 'insufficient evidence' can justify diametrically opposite outcomes. The EU approved E142 with an ADI of 5 mg/kg despite EFSA explicitly noting inadequate chronic toxicity data, while the USA, Japan, and Canada banned it precisely because the safety database was too thin to establish confidence. This case reveals a core philosophical divide: whether the burden of proof should fall on demonstrating harm (EU approach) or demonstrating safety (precautionary bans), with JECFA's refusal to establish any ADI underscoring how the same data gap was read differently by every major regulatory body.
Detailed Regulatory Assessment
European Union (EFSA)
Limited uses; permitted in specific food categories only
Official EFSA LinkUnited States (FDA)
Never authorized for use in food, drugs, or cosmetics
Japan (MHLW)
Not approved for food use in Japan
Acceptable Daily Intake (ADI)
International Standard (JECFA)
mg/kg body weight per day
European Standard (EFSA)
Everyday Perspective
For a 60kg adult, this limit is roughly equivalent to consuming:
Natural Occurrence
This additive is not known to occur naturally in significant quantities.
Manufacturing
Synthesized through sulfonation of aromatic amine intermediates derived from petroleum-based chemicals. The reaction produces a synthetic triarylmethane dye that appears as dark blue/dark green powder and yields bright green colour when dissolved in water or other solvents.
Applications Beyond Food
Limited use in some jurisdictions
Textile dyeing (historical use)